Standard Pressure Volume Temperature Data for Polymers

by David Walsh

From the Introduction

PVT data consists of records of the specific volume of a material (or its inverse, the density) as a function of pressure and temperature. There are many reasons why the specific volume of a material will undergo changes in the temperature and pressure (thermal expansion and compression), phase changes (solid-solid phase transitions, melting, crystallization, glass transitions, mesophase transitions), degradation reactions, and many more. Conversely, PVT measurements can be used to study these phenomena and also to yield derivative data of direct importance to engineering applications of materials (compressibility, bulk modulus, thermal expansivity, etc.).
PVT methods are part of a wide array of thermoanalytical techniques available to scientists and engineers, but PVT is the only commonly practiced technique that includes pressure as a variable. Polymers are sensitive to the volume itself, the pressure dependence of transition temperatures, and the kinetics of phase transitions are all significant, not only from a scientific point of view, but also for practical applications in polymer engineering, such as processing.

Now published. This unique polymer reference book will be useful to all those involved in polymer research and advanced engineering. The more than 350 tables and graphs provide a wealth of important data in easy-to-use form. The introductory chapter provides details on methodology, equipment use, and information on the many ways in which PVT data can be used in research and engineering.

412 pages, Hardcover

First published August 24, 1995