This would be my recommendation to anyone who was going to read a single book on maths. Mac Lane gives a tour of mathematics, motivating it in terms of the questions: what does mathematics do, and what is it? I found this approach quite refreshing; the book reads more like a narrative than the typical theorem/proof reference.
Mac Lane is careful to put the question of 'what does mathematics do?' in terms of human activity. Counting, rearranging, measuring, moving, estimating, choosing, etc. - each of these is a human activity that Mac Lane then describes in terms of orders, groups, motion, topology, etc. At the same time, he develops the topics in a strangely 'natural' sequence from a pedagogical perspective - starting with sets and numbers and eventually concluding with categories and the nature of formal systems.
Readable and re-readable, and highly recommended.