I've read and reviewed a lot of these volumes from the Outward Odyssey over the last few years, and they're consistently of top quality, excellent histories of different aspects of space exploration backed by penetrating and often untold stories of the men and women involved, on the American and Soviet side, which is refreshing.
However in this volume the focus on personnel does not work in the book's favor, since the actual science achieved by programs like Luna, Mariner, Venera, Pioneer and, yes, goddammit, Voyager is endlessly fascinating, far more fascinating than much of the stories of the folks involved in the program, unfortunately. And yes, their stories are important, too, but if you'd rather read about what Voyagers did in the outer solar system and their discoveries instead of intra-office bitching over math problems, you'll want to look elsewhere.
As always the Soviet focus really shines here since that's a part of space exploration you really get a feel for. There's whole swathes of sections on S.P. Korolev and all the initial Russian leaps after Sputnik. Once the Voyager program kicks in, the Soviet focus fades away, and completely ignores achievements like Venera 13 landing on Venus and sending back the first photos from the surface of another world.
On the American side, a neat introductory part about James Van Allen and his work swiftly devolves into name after name of official and scientist doing thing after thing in place after place. As I already mentioned, Voyager gets zero focus on results and, shockingly Viking is barely mentioned at all. You get the drift...well written from one perspective, that weighs down the entire work to the neglect of the fascinating bits.