I must admit beforehand that this review may be biased as I consider Kline to be almost solely responsible for my career path and interest field in general. Kline's other book "Mathematics for the Nonmathematician" had an enormous influence on me and set me up on a lifelong journey to discover the nature of mathematics and the universe itself. A journey that I persistently follow to this day. Needless to say, I feel great respect for the author which might get in the way now as I try to objectively review his work. Nevertheless, I'll try to present my case as to why this book is the best calculus book out there.
The key aspect that differentiates this book from others is the approach Kline takes to teaching mathematics. Kline presupposes that mathematics is deeply rooted in the sense of intuition and it is from this side that any student should first approach this field. Rather than treating mathematics in an abstract form of symbol manipulation, Kline says that it is imperative to provide a meaning for those symbols first, to give a context for the equations to exist. Kline does all that by considering real-world phenomena: a falling object, a moving car, a swinging pendulum, etc. Now you might say that all calculus books have these kinds of examples and there's nothing special in that. But the difference here is that all those books consider physical reality afterwards, often leaving it as an exercise in theory application, while Kline places it front and centre. Looking from the historical perspective, this is exactly how mathematics and indeed calculus itself was developed - by trying to solve real-world problems. Rigour was added much later.
The benefits of this intuitive approach are twofold. First is the clarity and ease of understanding that the student gets by learning the subject with respect to something he can relate to. It's incredibly difficult (at least for me) to make sense of all these abstract quantities that mathematics is full of. But thankfully, it needn't be so as intuition when correctly developed can be just as good as a guide.
The second benefit of taking Kline's approach is that the book becomes actually readable. To understand this point, you just have to open any calculus textbook you'll find in any university recommended book list (Stewart's Calculus will do just fine) and attempt to read a page or two. If you're like me, the book will read like the driest technical manual devised for a single purpose only - to help students solve their calculus class problems and no more than that. We have the usual structure: a list of axioms, followed by a theorem, then its proof, then some abstract exercises and the pattern repeats. An intuitive understanding here is left for the student to develop as an additional exercise. You'll not find this in Kline's Calculus. He provides not only the reasoning behind the mathematical ideas but also their historical context and evolution which they underwent as they were being developed. For myself, being a history buff, it's immensely interesting.
Now, this book is not a conventional calculus textbook and not only because of all the reasons I've already listed. The range of topics covered in the book includes some topics of what these days is considered a part of algebra (plain geometry etc). But in my view, that's only an advantage as it's explained so masterfully well. Still, I'd say that the book is best suited for a person who's just starting to learn calculus and wants to do it the right way. Graduates might miss some more advanced topics like differential equations and Fourier series as they are not covered in the book, or are mentioned briefly.
In summary, I cannot praise Kline's Calculus highly enough. It is wholly unique in its approach and clarity. I cannot think of a better introduction to the ideas of calculus than what this book presents.