Studies in Surface Science and Catalysis, Volume 95: Catalysis by Metals and Alloys

by Vladimir Ponec, Geoffrey C. Bond

Hardbound. The theoretical basis of chemisorption and catalysis by metals and alloys, and their use in a range of model and industrially significant catalysed processes are described in this book.Model, as well as industrially used reactions catalyzed by alloys are reviewed, among them the Fischer-Tropsch synthesis, reactions of alkanes ('reforming'-reactions), oxidations, hydro-/dehydrogenation, decomposition of methanoic acid, deuterium exchange reactions (H2, hydrocarbons) and to a lesser extent some others. This review on catalytic reactions, with results from the available information, is introduced in two chapters which summarize the definition, the physical meaning and the role of such factors as ligand (electronic structure), ensemble size (geometrical) and ensemble composition effects. The assessment of the roles of these individual factors requires the knowledge of several physical techniques and a proper evaluation of the results

744 pages, Hardcover

First published August 1, 1995