Part 1: Getting Started 1. What is DevOps? 2. Introducing Azure and Visual Studio Team Services Part 2: Plan 3. Agile Project Management 4. Managing user feedback 5. Advanced Agile Project Management 6. Dashboards and Reporting Part 3: Code & Build 7. Setting up Version Control 8. Managing Technical Debt 9. Implementing Continuous Integration 10. Creating and sharing packages Part 4: Test, Deploy, and Monitor 11. Integrating testers into DevOps 12. Implementing Continuous Delivery 13. Using Application Insights 14. Where to start
It has a nice overview of all the capabilities of Microsoft TFS and its administration. If you want indepth analysis, this may not be the right book to read