The Art of Writing Reasonable Organic Reaction Mechanisms

by Robert B. Grossman

Intended for students of intermediate organic chemistry, this text shows how to write a reasonable mechanism for an organic chemical transformation. The discussion is organized by types of mechanisms and the conditions under which the reaction is executed, rather than by the overall reaction as is the case in most textbooks. Each chapter discusses common mechanistic pathways and suggests practical tips for drawing them. Worked problems are included in the discussion of each mechanism, and "common error alerts" are scattered throughout the text to warn readers about pitfalls and misconceptions that bedevil students. Each chapter is capped by a large problem set.

Genres: Chemistry, Science, Reference, Nonfiction

376 pages, Hardcover

First published January 1, 2002

Reviews

[Robert Vincent · Rating 5 out of 5]

I am a chemist by education and occupation but I have always had difficulty figuring out the most reasonable (very aptly chosen word for the title) reaction mechanism for whatever organic reaction I run across. Sure, I can come up with a reaction mechanism but sometimes the mechanism I come up with does not hold up to scrutiny. I bought this book to try to better myself in that regard. The book itself is a little learning course, complete with exercises (answers are online) that progresses at a reasonable pace. I was able to follow through on my own and come out of reading (and studying) this book much better able to apply the knowledge I already had in a more focused manner. I would highly recommend this text for anyone trying to better their own understanding of reaction mechanisms or people that have difficulty picking a favorite of many possible reaction paths.

[Harish Suryadevara · Rating 5 out of 5]

An excellent introduction to more complex topics in organic chemistry - the use of molecular orbital explanations throughout are particularly useful. Section on pericyclic reactions and free radical chemistry are great introductions to the subjects, and the reaction problems are challenging yet useful. The section on organometallic chemistry seems a bit crammed - I would use a separate book if you're interested. Overall, great book - certainly worth reading if you're interested in learning more about organic chemistry

[Bella Liffick · Rating 1 out of 5]

He's no David Klein

[Sanjay Pandiri · Rating 4 out of 5]

Good textbook. Grossman disrespects the cyclopropylmethyl cation, however.

[Harrison · Rating 5 out of 5]

beautiful!

[Senka Colo · Rating 5 out of 5]

I found this book to be probably one of the best books out there on the topic.