While there are a few places where notation and time make it more difficult to understand Maxwell's explanations, for the most part it is astounding how modern Maxwell's presentation of the concepts is. Volume 1 is all about electrostatics and "electrokinetics" (i.e., circuits with constant currents). The book covers much of what is still covered today, although it has a lot more on the image charge method (the method of inversion, generally).
This is worth reading for historic value, but if you want to be up to date on electricity and magnetism, you should consult a more recent textbook. Otherwise you will probably struggle to understand what Maxwell is doing for he eschews vector notation which can make some equations seem much more cluttered. However, if you want to see the development and what was known in the 1870s, this is a great volume that is concise, offers interesting explanations, and historical knowledge and development.